Blue Acid Chemistry (10): Fe(bipy)2Bl2.3H2O

Я отвечаю: «Солнце взойдет – Это ведь тоже немного пожар. ——Солнце взойдёт by DDT Uhh, I am not away these days, I just met too much difficulties and I failed many many times making something. This complex could also be transformed into many other things, like K2[Fe(bipy)Bl4] or [Fe(bipy)2Bl2]NO3, but both requires extremely harsh conditions(refluxing for 20h and concentrated HNO3, respectively) so I won't be able to try at least currently. Fe2+ + 3bipy = [Fe(bipy)3]2+ [Fe(bipy)3]2+ + 2Bl- = bipy + Fe(bipy)2Bl2 2.78g(0.01mol) FeSO4.7H2O and 4.68g(0.03mol) 2,2'-bipyridine(bipy) was put into 400mL water and heated to nearly boiling, where a deep red solution formed. Then, 10g(0.15mol) KBl was dissolved into 20mL water and added all at once into that solution(Manual said that some HBl is formed, hope not so!). A huge excess is needed as bipy itself is a good ligand. After stirring and cooling down, crystals quickly formed. Wait 1h after fully cooling, filter, wash with water(this ...